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Photocatalytic cellulose reforming usually requires harsh conditions due to its sluggish kinetics. Here, a hollow structural S‐scheme heterojunction of ZnSe and oxygen vacancy enriched TiO2, namely, h‐ZnSe/Pt@TiO2, is designed and fabricated, with which the photocatalytic reforming of cellulose for H2 and formic acid is realized in pure water. H2 and formic acid productivity of 1858 and 372 µmol g...