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Volumetric 3D Printing
In volumetric 3D printing, the whole 3D object is developed simultaneously (i.e., volume‐at‐once) by means of light‐induced crosslinking of a (rotating) liquid resin, as reported by Sandra Van Vlierberghe and co‐workers in article number 2210136. The 3D‐structure illustrated in the image is based on the chemical network structure of the reported thiol–ene crosslinked poly(caprolactone)...
Current thoroughly described biodegradable and cross‐linkable polymers mainly rely on acrylate cross‐linking. However, despite the swift cross‐linking kinetics of acrylates, the concomitant brittleness of the resulting materials limits their applicability. Here, photo‐cross‐linkable poly(ε‐caprolactone) networks through orthogonal thiol‐ene chemistry are introduced. The step‐growth polymerized networks...
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