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Molecular doping of conjugated polymers (CPs) is critical to improve their electrical properties in organic thermoelectric materials, which are promising candidates for low‐temperature energy harvesting and self‐powered sensors. Because excessive dopants are used in the doping process, securing highly crystalline CPs by suppressing dopant‐induced disorder is crucial. Recently, tris(pentafluorophenyl)borane...
A high power factor must be achieved to improve the thermoelectric (TE) output of organic TE materials though the tradeoff between electrical conductivity and the Seebeck coefficient is a serious obstacle to the further development of these materials. Here, systematic control of the electrostatic interaction between a conducting polymer and a dopant induces a positive deviation from this TE tradeoff...
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