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A “three birds, one stone” strategy is proposed to enhance the performance of hematite photoanode for photoelectrochemical water splitting. One‐pot hybrid microwave synthesis of Ta and Sn codoped Fe2O3@FeTaO4 core–shell nanorods on F:SnO2 substrate achieves three synergetic effects simultaneously: i) core–shell heterojunction formation to alleviate the significant electron–hole recombination; ii)...