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The kinetics of the complex formation reactions between monofunctional palladium(II) complex, [Pd(dien)Cl]+, where dien is diethylene triamine or 1,5-diamino-3-azapentane, with L-cysteine and glutathione were studied in an aqueous 0.10M perchloric acid medium by using variable stopped-flow spectrophotometry. Second-order rate constants, ${k_2}^{298}$, were (3.890.02) 102M1s1 for L-cysteine and (1...