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This paper provides a concise, introductory review intended mainly for Mössbauer spectroscopy (MS) scientists not familiar with the most modern aspects of High Pressure (HP) methodology. Following a short introduction to the 1st generation HP-MS based on Drickamer’s pressure cells, we describe the principles of the 2nd generation of HP-MS based on the Diamond Anvil Cell (DAC) including in-situ pressure...
Combining the methods of Mössbauer spectroscopy, synchrotron XRD, and resistivity and using diamond-anvil cells enables the discovery and studies of new phenomena in magnetism and electronic correlation at high density. It is shown that Hund's rule concerning the high-spin state in TM-compounds does not hold in this regime resulting in spin-crossover and collapse of the magnetic state for even-valence...
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