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The process of formation and the characteristics of silver nanostructures created by pulsed laser annealing in the air are studied. Nanoparticles were obtained by way of irradiating thin silver films (62 and 175 nm) on the dielectric (glass) base with an excimer laser emission (λ = 193 nm). Created nanostructures were studied using the methods of scanning electron microscopy and optical spectrometry,...