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The behaviour of binary mixtures of ammonium perfluorooctanoate with ammonium octanoate, ammonium decanoate and ammonium dodecanoate at the air-water interface has been investigated in detail by surface tension measurements. These were carried out both below and above the critical micelle concentration for mixtures containing mole fractions of the alkanoate ranging from zero to unity. It was found...
Abstract The size and shape of ammonium decanoate and ammonium dodecanoate micelles as functions of micellar concentration have been studied using the techniques of small-angle neutron scattering and time-averaged light scattering. The results indicate that the micellar mass of ammonium dodecanoate increases with surfactant concentration. This behaviour can be attributed to the formation of rod-like...
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