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Enthalpy of charging of hematite surface was determined by calorimetry and also by measuring the dependence of the point of zero charge (p.z.c.) on temperature. The calorimetric experiment was designed in such a way that the point of zero charge was in the middle between the initial and final pH. In that case, the reaction heat corresponds to the difference in standard reaction enthalpies of surface...
Surface Complexation Model was applied for the analysis of counterion association in the micellar systems. The equilibrium in cetyltrimethylammoniumbromide (CtaBr) solution was examined. Thermodynamic equilibrium constant was calculated using experimental data obtained with ion-selective electrodes (silver/silver bromide and surfactant electrode).
Surface Complexation Model was applied for the analysis of counterion association in the micellar systems. The equilibrium in cetyltrimethylammoniumbromide (CtaBr) solution was examined. Thermodynamic equilibrium constant was calculated using experimental data obtained with ion-selective electrodes (silver/silver bromide and surfactant electrode).
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