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Abstract Ribbons of the metal-metalloid glassy alloy (Fe,Cr)80(P,C,Si)20 and Fe75Cr5P8C10Si2, respectively, were treated with an aqueous solution of FeCl3 (29 mass%) in an ultrasonic bath. The surface of the amorphous solid is maximally influenced at the flux line as the contact zone of glass/solution/ air. This region of the amorphous solid was studied by light microscopy, scanning electron microscopy...