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The charge transfer complex (CTC)tetrathiafulvalene-9-dicyanomethylene-2,4,5,7-tetranitrofluorene(DT4NF) displays a degree of charge transfer Z = 0.7.This value is situated close to the border between intermediateand strong CTC's. Under the view, that CTC's with values 0.4 <Z < 0.7 in general are molecular electrical conductors, fourdifferent CTC's were prepared formed of tetrathiafulvalene...
The charge transfer in charge transfer complexes, based on Zinc-naphtholimines (Zn[RNAFIN]2) with TCNQ is studied in the present paper. New electronic states form with the effect of corresponding transition bands in vibrational spectra. This proves the existence of mixed valence complexes. Band peak shifts in the visible spectral region are manifest, which provide for the evaluation of the charge...
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