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Ground waters in North Hesse (Germany) are conspicuous by high amounts of dissolved inorganic carbon (DIC) at low pH. The DIC is received from the uptake of soil CO2 and CO2 of volcanic origin and the subsequent dissolution ofTriassic and Permian limestone and dolomites. The volcanic CO2 is related to Miocene basaltic magma which has liberated gaseous CO2 during thebreakthrough to Triassic and Permian...