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The complexcis-[Ru(bpy)2(PMe3)Cl+][ClO4−] crystallizes in space group P21/c andcis-[Ru(bpy)2{PMe2(o-tol)]Cl+][ClO4−] crystallizes in space group $$P\bar 1$$ ; each is present as a racemate and neither structure suffers from disorder. The Ru−PMe2(o-tol) bond length of 2.324(2)Å is slightly longer than the simple Ru−PMe3 bond length of 2.310(2) Å.