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Replication is a strategy in which multiple copies of same data are stored at multiple sites. Replication has been used in cloud storage systems as a way to increase data availability, reliability and fault tolerance and to increase the performance. Number of replicas to be created for a file and placement of the replicas are the two important factors which determine the storage requirement and performance...
Total synthesis of (±)-thallusin was achieved using Hg(OTf) 2 ·PhNMe 2 -induced olefin cyclization, and Suzuki coupling with a pyridylboronic acid derivative. Hg(OTf) 2 also acted as a catalyst to isomerize the double bond into the more thermodynamically stable isomer when treated in toluene. Synthetic (±)-thallusin as well as an analogue showed morphogenesis-inducing activity.
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