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New fluoroalkylated end-capped 2-acrylamido-2-methylpropanesulfonic acid copolymers containing poly(oxyethylene) units were prepared by the use of fluoroalkanoyl peroxides. It was demonstrated that these fluorinated copolymers can form gels in DMSO under non-crosslinked conditions, and these fluorinated polymeric gelling electrolytes containing lithium salts exhibit a considerably high ionic conductivity...