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Tenatoprazole, a substituted imidazopyridinyl derivative, is an irreversible proton pump inhibitor (PPI), which is used for the prevention and treatment of gastric acid-related diseases. A new highly efficient asymmetric oxidation using cumene hydroperoxide (CHP) as the oxidant in the presence of titanium tetraisopropoxide (Ti(OiPr) 4 ) and (+)-(1R,2S)-cis-1-amino-2-indanol, in a polar aprotic...
A series of para-substituted N-allylbenzamides was submitted to isomerization under basic conditions. With LDA at −78°C, the corresponding (E)-N-(prop-1-enyl)benzamide was the major product. With n-butyllithium and the mixture warmed to 0°C, the (Z)-isomer was essentially furnished.
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