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In the gas phase 4-picoline is a much stronger base than pyridine (ΔpK B =2.9) and consequently it forms much stronger complexes with CoCl 2 . Using high temperature visible absorption spectroscopy we determined the enthalpy of the gas phase reaction CoCl 2 (g)+L(g)=CoCl 2 L(g) as -233 kJ mol -1 for L=4-picoline and -156 kJ mol -1 for L=pyridine...
In search of a reversible magnesium electrode at ambient temperature the solubilities, conductivities and reduction potentials of nine magnesium compounds, including MgCl 2 , Mg(CF 3 SO 3 ) 2 and Mg-acetylacetonate, were studied in 20 aprotic organic solvents (N- and O-donors) and 70 of their mixtures[l]. Although the goal was not reached, electrochemical dissolution...
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