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The adsorption and decomposition of ethanol on Pd(110) has been studied by use of a molecular beam reactor and temperature programmed desorption. It is found that the major pathway for ethanol decomposition occurs via a surface ethoxy to a methyl group, carbon monoxide and hydrogen adatoms. The methyl groups can either produce methane (which they do with a high selectivity for adsorption below 250...
A molecular beam and temperature-programmed desorption study of methanol, ethanol and 2-propanol has been performed on oxygen pre-covered Pd(110). Two reaction pathways have been identified for all the alcohols studied. The main one involving the formation of water, CO 2 , CO and hydrogen, the other involving C(ad)+O(ad) recombination caused by the alcohols undergoing C-O bond scission. In...
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