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A novel electroactive/AIE-active polymer with tetraphenylethylene (TPE) and triphenylamine (TPA) units was prepared from a newly synthesized diamine, 4-tetraphenylethyleneoxy-4′,4″-diaminotriphenylamine, and cyclohexanedicarboxylic acid. By ingenious introduction of ether linkage between TPE and TPA units, the obtained polymer simultaneously exhibited high solid-state fluorescence, colorless neutral...