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In this work, Cu2ZnSnS4 (CZTS) thin film was successfully prepared from four types of mixed binary sulfides nanoparticles under inert Ar atmosphere. A comparison study was conducted to explore the effect of binary sulfides with different value states on the CZTS thin films. Through X-ray diffraction (XRD), Raman and scanning electron microscopy (SEM), the pure CZTS phase can be obtained independent...