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Five trinuclear substituted complexes of the type Ru 3 (CO) 11 L, Ru 3 (CO) 10 L 2 and Ru 3 (CO) 9 L 3 were synthesised by the reaction of Ru 3 (CO) 12 with fluorine substituted phosphine ligands, {P(C 6 H 4 F-m) 3 and P(C 6 H 4 F-p) 3 }, using the radical anion catalysed...
Five trinuclear monosubstituted complexes of the type Ru 3 (CO) 11 L were synthesised by the reaction of Ru 3 (CO) 12 with phosphine ligands (L) using the radical anion catalysed method. The structures of the resulting clusters were elucidated by means of elemental analyses and spectroscopic methods, including IR, 1 H NMR, 13 C NMR and 31 P NMR...
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