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Cyclometalation of benzo[h]quinoline (bzqH) by [RuCl(μ-Cl)(η 6 -C 6 H 6 )] 2 in acetonitrile occurs in a similar way to that of 2-phenylpyridine (phpyH) to afford [Ru(bzq)(MeCN) 4 ]PF 6 (3) in 52% yield. The properties of 3 containing ‘non-flexible’ benzo[h]quinoline were compared with the corresponding [Ru(phpy)(MeCN) 4 ]PF 6 (1) complex...
Yellow cyclometalatated ruthenium (II) complexes [Ru(o-X-2-py)(MeCN) 4 ]PF 6 (1, X=C 6 H 4 (a) or 4-MeC 6 H 3 (b)) react readily with 1,10-phenanthroline (LL) in MeCN to give brownish-red species cis-[Ru(o-X-2-py)(LL)(MeCN) 2 ]PF 6 in high yields. The same reaction of the same complexes under the same conditions with 2,2′-bipyridine results...
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