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Stereo-electronic effects in through-bond tunneling in large area molecular junctions have not been widely studied, largely due to a lack of a clear understanding of basic interfacial properties of self-assembled monolayers (SAMs) — the platform on which these junctions are built. Due to a large volume of work in SAMs, it has been largely assumed that their characteristics are well understood, among...
Chemical grafting of small molecule reagents onto polymeric fibrous materials, like paper, has been used to modify their wetting properties. Several reagents like trichlorosilanes, which can react with water or hydroxyls, have been used with the expectation that a monolayer, single molecule or polymerized single-molecule layer, is formed on the paper fiber surface. Presence of adsorbed water, however,...
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