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Although an interaction between hydrocarbon and fluorocarbon 1,3,2,4‐benzodithiadiazines (1 ) and P(C6H5)3 continuously produces chiral 1,2,3‐benzodithiadiazol‐2‐yl iminophosporanes (2; in this work, 5,7‐difluoro derivative 2a ) via 1:1 condensation, an interaction between 1 and other PR3 reagents gives different products. With R OC6H5 and both hydrocarbon and fluorocarbon 1, only X=P(OC6H5)3 (X...
The reactions of Ar–Se–N=S=N–Se–Ar with SO 2 Cl 2 (as well as with ArSeCl and p-TolICl 2 ) and H 2 O gave Ar–SeCl 2 –N=S=N–Se–Ar and [NH 4 ] + [ArSeSO 3 ] – (Se-Bunte salts), respectively, whose structures were confirmed by X-ray diffraction.
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