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To study the effect of the conformation of sugar hydroxy groups on metal complexation processes, complex formation of eight saccharides (D-fructose, L-sorbose, L-arabinose, D-arabinose, D-glucose, D-sorbitol, 2-deoxy-D-glucose and D-saccharose) with dimethyltin(IV) cations was investigated in aqueous solution by potentiometric equilibrium measurements, 13 C NMR, polarimetric and Mossbauer...
Complex formation between oxovanadium (IV) and several diazole derivatives (imidazole-4-acetic, imidazole-4,5-dicarboxylic and pyrazole-3,5-dicarboxylic acid) was studied in aqueous solution by pH-potentiometric and spectroscopic (electron paramagnetic resonance and electronic absorption) techniques. The results show that the imidazole-4-acetate ligand, being suitable for bidentate coordination,...
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