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The marine actinomycete Williamsia sp. MCCC 1A11233 was isolated from a deep sea sediment sample of the southwestern Indian Ocean. It was closely related to Williamsia limnetica L1505T with a 16S rRNA gene sequence similarity value of 99.2%. A systematic investigation on its chemical constituents was performed in this study, which led to the isolation of one new (1) and 23 known (2–24) secondary metabolites...