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We report thermal desorption spectra for acetyl chloride (CH 3 COCl) adsorbed on Cu(111), and find that the adsorption is irreversible at low coverages. Using a chemical displacement technique we estimate an activation energy of 39 kJ/mol for a reaction at low coverages of adsorbed acetyl chloride to form a more strongly bound surface species. We also observe that the co-adsorption of iodobenzene...
The bonding and reactions of chloroethylenes (vinyl chloride, trans- and cis-dichloroethylene, trichloroethylene) on a Cu(100) surface have been investigated by temperature-programmed desorption and reaction, near-edge X-ray absorption fine structure (NEXAFS) studies and measurements of changes of the surface work function. The monolayer molecules adsorb molecularly intact at 95 K via π coordination...
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