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Nonstoichiometric ordered network polymer-surfactant complexes (NPSC) formed by slightly cross-linked networks of poly(diallyldimethylammonium chloride) (PDADMACL) and oppositely charged surfactant of sodium dodecylbenzenesulfonate (SDBS) were obtained. The structure of NPSC was studied by SAXS. At the excess of SDBS in the presence of low-molecular-weight salt, sodium chloride, the complexes can...