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Photodissociation dynamics of H2O2 at 205nm producing H atoms has been investigated by measuring laser-induced fluorescence spectra of H. From Doppler profile analyses, the average translational energy release was found to be 150.4±70.1kJ/mol with the anisotropy parameter, −0.35±0.05 for the characteristic perpendicular transition. Potential energy surfaces for the S0, S1, and T1 electronic states...