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Conversion electron and X-ray backscattering Mossbauer spectroscopy was used to identify iron compounds that were formed on carbon steel in simulated CANDU reactor coolant containing 15 to 60 ppb (μg/L H 2 O) soluble zinc. Analyses of the coupons exposed to coolant in the absence of zinc indicated the formation of magnetite, whereas, in the presence of zinc, the formation of a layer of zinc-bearing...