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Ferromagnetic thin films of single domain core–shell α″-Fe16N2/Al2O3 nanoparticles (NPs) with average size of 47nm were prepared by spin coating of the NPs which were well-dispersed to the primary NPs size in toluene by low energy bead-mill dispersion. The magnetic orientation (perpendicular to the Si substrate) was set by applying a magnetic field of 1.2T during the film formation with a thickness...