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The ARID is an ancient DNA-binding domain that is conserved throughout the evolution of higher eukaryotes. The ARID consensus sequence spans about 100 amino acid residues, and structural studies identify the major groove contact site as a modified helix-turn-helix motif. ARID-containing proteins exhibit a range of cellular functions, including participation in chromatin remodeling, and regulation...
The easily prepared bishomosecoheptaprismane ring system of 1 was converted to the tetracyclo[8.5.0.0 2,8 .0 7,11 ]pentadeca-3,5,12,14-tetraene ring system of 10 using a photochemical decarbonylation/fragmentation reaction as the key step. The closely held face-to-face butadiene units in 10 undergo [4+4]cycloaddition under photochemical conditions and participate...
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