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We studied the temperature dependence of the Raman scattering spectra of two semiconducting, isostructural charge transfer salts κ-[Et 4 N](BEDT-TTF) 4 M(CN) 6 .3 H 2 O (M = Co III , Fe III ) within the region of C=C stretching vibrations (1200-1700 cm -1 ). Moreover, polarised reflectance spectra (600-10000 cm -...
Infrared and Raman spectral properties of the organic composites obtained by direct solid-solid charge-transfer (CT) reaction between bis(ethylenedioxy)tetrathiafulvalene (BEDO-TTF) and iodine are investigated for the first time. The band attribution, an evaluation of the average charge on the donor molecule, changes of the BEDO-TTF spectra after composite formation and an analysis of the plasma-edge-like...
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