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Conductivity measurements of polycrystalline CsH 2 PO 4 and CsH 2 PO 4 /silica composite were carried out in the temperature range from 150 to 250 o C under a humid condition. A steep change in the conductivity of polycrystalline CsH 2 PO 4 due to a phase transition from a low conductive phase to a high conductive phase (superionic conduction...