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The photodissociation of hexafluoropropene at 193 nm was studied using photofragment translational spectroscopy. One primary channel results in loss of a fluorine atom; from the maximum translational energy release, a value of 121 kcal/mol was determined to be the upper limit for the C-F bond dissociation energy. In addition, elimination of CF 2 and CF 3 competes with C-F bond cleavage...