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The photodetachment cross sections of the C2H− and C4H− molecular anions in their ground electronic and vibrational states are determined using the R-matrix approach. The obtained results are compared with available experimental data of absolute photodetachment cross sections. In addition, cross sections for the inverse process, i.e., radiative electron attachment, have also been determined and are...
We report two different assignments of the vibrational structure of the Ar-NO + cation observed by Takahashi. On one hand, the ab initio potential energy surface (PES) of Robbe et al. (Chem. Phys. Letters 210 (1993) 170) allows us to interpret the main observed features as arising from a Fermi-type interaction between the stretching progression (v s ,v b = 0) and the (v ...
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