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Taking the fingerprint characteristics of Raman spectroscopy, the dimerization of p‐nitrothiophenol (PNTP) to 4‐nitrophenyl disulfide in air was investigated, which could be accelerated by the external laser illumination. The dimerization was qualitatively confirmed by both mass spectroscopy experimentally and by Raman spectrum simulated calculations theoretically and quantitatively analyzed by Raman...
We demonstrate an electrochemically assisted mechanically controllable break junction (EC-MCBJ) approach for current-voltage characteristic (I-V curve) measurements of metal/molecule/metal junctions. A series of oligo(phenylene ethynylene)s compounds (OPEs), including those involving electron withdrawing substituent group and different backbone lengths, had been successfully designed, synthesized,...
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