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Corrosion behavior of Fe–3at.% Si alloy in 0.01moldm −3 HCl solution was investigated by using scanning electrochemical microscopy (SECM) as well as general electrochemistry. The rate of corrosion coupled with hydrogen evolution was initially 0.44Am −2 but decreased significantly with time. Localized hydrogen evolution on the specimen surface was probed by an SECM system in which a...