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In poly(ε caprolacton) (PCL)/poly(vinyl butyral) (PVB) blend which forms band spherulite, some straight lines along the radial direction of the spherulites are observed under polarized optical microscope (POM). By using microbeam scanning WAXS, we have investigated the handedness of lamella twisting on the left and right sides of the straight line. As a result, we have observed that the manner of...
The microbeam small- and wide-angle X-ray scattering (SAXS/WAXS) technique gives the novel information about micron-scale structural inhomogeneity of polymer crystal. By using this technique, we have studied structural inhomogeneity of lamella within the band spherulite of miscible polymer blend poly(ε caprolactone) (PCL)/poly(vinyl butyral) (PVB) and the structure development of lamella during crystallization...
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