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The thermochemistry of several ion-molecule clustering reactions of HCNH + , HCNH + (N 2 ) and HCNH + (CH 4 ) ions with C 2 H 2 was determined from chemical equilibrium measurements. Inorder to better understand the chemistry of Titan, a gas mixture containing 97% N 2 , 3% CH 4 anda small amount of 0.005% C 2 H 2 ...