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Online upgrading of the obtained vapour from fast pyrolysis of sugarcane bagasse over sodium-based catalysts was studied in a fixed-bed reactor at 500°C. Over Na2CO3/γ-Al2O3 catalyst, both its physico-chemical properties and concentration of sodium salt play significant roles in its performance. Larger pore size is advantageous since it was shown to facilitate the conversion of lignin-derived high...