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A new, adsorption-based mechanism of potentiometric response of the plasticized PVC membranes is proposed. In contrast to previous mechanistic studies of the membrane-based Ion-Selective Electrodes (ISE), the membranes in this study did not contain any purposely-added additives: lipophilic salt or ionophore. Cationic or anionic response of such “blank” ISEs was observed upon contact with ionic surfactants:...
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