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This work describes a procedures to grow single phase Cu2ZnSnS4 (CZTS) thin films with tetragonal-kesterite type structure, using solution and vacuum based deposition techniques. The solution based deposition approach involves sequential deposition of Cu2SnS3 (CTS) and ZnS films, where the CTS compound is synthesized in one step process by simultaneous precipitation of Cu2S and SnS2 performed by diffusion...
This paper present a new method for growing thin films of CZTS using a solution-based chemical route; this consist in sequential deposition of Cu2−xS, SnS and ZnS films by CBD followed by annealing in nitrogen atmosphere. The Cu2−xS and SnS precursors were deposited by diffusion membranes assisted CBD technique and the ZnS by conventional CBD method. Diffusion membranes are used to optimize the kinetic...
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