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We propose to develop an approach that may easily provide potentially complementary surfaces with a given recognition interface by assembling chemical groups to a scaffold in a combinatorial manner. In that way, we here present the concept of template-directed combinatorial surface assembly. The principle of the approach, the synthesis of libraries and the methods used to characterize the mixture...
Thiazolidines, especially the 2,2-dimethylated residue Cys(Ψ Me,Me pro), are efficient tools to lock Xaa-Pro amide bond to the cis conformation. We investigated herein a new synthetic approach to incorporate these proline mimics instead of the proline into a peptide sequence using Nα-protected derivatives by a fluorenylmethyl or an allyl carbamate. To cite this article: S. Chierici et al.,...
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