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Living free radical polymerization technology (macromolecular design via the interchange of xanthates (MADIX)) was applied to give accesses to chain length and conversion dependent termination rate coefficients of vinyl acetate (VAc) at 80°C using the MADIX agent 2-ethoxythiocarbonylsulfanyl-propionic acid methyl ester (EPAME). The kinetic data were verified and probed by simulations using the PREDICI...
The reversible addition fragmentation chain transfer-chain length dependent-termination (RAFT-CLD-T) methodology was employed to map chain length dependent termination rate coefficient, kti,i, in dodecyl acrylate (DA) free radical polymerization at 60 and 80°C. The chain length of the propagating DA radicals was controlled by the RAFT agents methoxycarbonylethyl phenyldithioacetate (MCEPDA) and dimethoxycarbonylethyl...
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