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The Mn3s X-ray photoelectron spectra of manganites were studied. It was shown that for the formal valence of manganese from 3+ to 3.3+, the doping holes are O2p in character; as the valence of manganese increases further, the Mn3d states acquire holes. For La0.7Sr0.3MnO3, the Mn3p-3d resonance spectra provided information about the occupied and unoccupied Mn3d states, and the correlation energy U...
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