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In honor of the awardee Dr. Teruo Umemoto and his significant advances in the preparation of pentafluorosulfanylbenzenes [1], we will first overview our results aimed at understanding the importance of copper (and other coinage metals) in W.A. Sheppard's original synthesis of SF 5 -benzenes [2] as well as a new route to SF 5 -benzenes involving the direct fluorination of aromatic sulfenyl...
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