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Although perfluorinated hydrocarbons are well known, they have only recently found application in organic chemistry as a useful class of solvents. Their physical properties make them unique for their use as reaction media. Since perfluorocarbons are immiscible with many common organic solvents, they are suitable for the formation of biphasic systems. This overview describes the utilization of perfluorocarbons...
In recent years the choice of a given solvent for performing a reaction has become increasingly important. More and more, selective reagents are used for chemical transformations and the choice of the solvent may be determining for reaching high reaction rates and high selectivities. The toxicity and recycling considerations have also greatly influenced the nature of the solvents used for industrial...
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