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Several aspects of the intercalation of organic dyes into DNA are presented. After a description of general features of intercalation and the analytical evaluation of this binding mode, recent applications of the intercalation process in chemistry, biology, pharmacy, and medicine are described, with examples from representative dye classes, namely acridines, anthraquinones, cyanines, and phenanthridinium...
Adults with congenital heart disease (CHD) are an increasing population requiring cardiac operations. To date, the perioperative risk factors for this group have not been identified. This study aimed to identify clinical, morphologic, and hemodynamic risk factors for an adverse outcome. This study retrospectively analyzed a cohort of 500 patients (ages >16 years) who underwent 543 operations between...
4-Aryloxymethyl-3-pyrrolines and their isomeric pyrrolidines––assembled via a one-pot, three-component coupling of propargylic amines, vinyl sulfones, and phenols––may be elaborated further to provide an easy access to 2,4-disubstituted pyrrole-3-carboxylates and 3,4-disubstituted pyrrolidin-2-ones. The latter were prepared by means of an unprecedented rearrangement process involving hydrogenolysis...
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