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Hydrogels based on thermo-responsive 2-(2-methoxyethoxy)ethyl methacrylate (pMEO2MA) are regarded as bioinert replacements of poly (N-isopropylacrylamide) in many biomedical applications. Here, we study kinetics of temperature-induced volume phase transitions (VPT) of pMEO2MA-based hydrogels of various network architecture during their water sorption and desorption processes by means of dielectric...
Copolymers of 2-(2-methoxyethoxy)ethyl methacrylate (poly(MEO 2 MA)) are regarded as bioinert replacements of poly( N -isopropylacrylamide) in some biomedical applications. Networks of poly(MEO 2 MA) of various architecture form thermo-responsive hydrogels. Here, we present dielectric and mechanical spectroscopy studies on segmental motions and network relaxation...
Thermoplastic elastomers based on well-defined 10- and 20 arm star-like block copolymers containing middle soft poly(n-butyl acrylate) (PBA) block and outer hard poly(α-methylene-γ-butyrolactone) (PMBL) block were synthesized by atom transfer radical polymerization (ATRP). Phase separated cylindrical or lamellar morphologies, depending on the copolymers composition and the annealing temperature of...
A series of well-defined triblock copolymers containing middle soft poly(n-butyl acrylate) (PBA) block and outer hard blocks of poly(α-methylene-γ-butyrolactone) homopolymer (PMBL) or random poly (α-methylene-γ-butyrolactone)-r-poly(methyl methacrylate) copolymer (PMBL-r-PMMA) were synthesized by atom transfer radical polymerization (ATRP). Phase separated morphologies of cylindrical or spherical...
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